Running a VPN server on your internal network allows you to build a secure tunnel between a remote device and your internal network. When the remote device it connected to your VPN the remote device appears as if it is inside your local network and gets an IP address from your internal network. Imagine if you will your android device while you are at home. The android device gets its IP address from your home router (presumably) and your BI machine thinks it is on your local network thus the BI app uses the IP address that you configured for use on your LAN (within the BI app itself). When you are on the go using your android device you are obtaining the IP address from the service provider that you pay to provide your data (ATT, Verizon, T-Mobile, etc). Since this IP address is not the same one as you get when you are home from your home router, BI uses the WAN address that you configured in the BI app settings to connect to your server. This WAN IP address is the address that you have from your internet service provider (Cox, Comcast, etc).
Now lets say you are on your android device out and about but instead of using the WAN address for your home's IP address, you instead connect to your home VPN server. There is a tunnel that is built between your android device and your home VPN server (the connection is Cell Provider to Home Internet Provider) but your android device believes that it has an IP address that is inside your home network. Also, your home network believes that your android device is at home and treats your android device as such. So when you are connected to BI through your home VPN server BI assumes you are home and uses the LAN configured IP address.
To answer your actual questions (1) you use the BI app just like you would if you are home while you are connected to your home VPN server and (2) connecting to the VPN server is not possible via the BI app. The establishing of the secure tunnel to your VPN server is done through other means on your android device. Anymore these days a VPN feature is baked into mobile devices (most electronics really that have a full feature OS running on it). So you first have to establish your secure tunnel to your VPN via the android device built in means (or third party app) and then use the BI app to connect to your server.
Hope that all makes sense.